Ozone depletion chemistry pdf notes

Sulfuric acid decomposition chemistry above junge layer in. The impact of very shortlived substances on the stratospheric. If interested, you can purchase this powerpoint from. These gases are carried to the stratosphere layer of atmosphere where. Halogen catalysis of ozone degredation halogens are a chemical family containing fluorine, chlorine, bromine and iodine. Finally, we briefly summarize the chemistry of polar ozone depletion. Using this model, tropospheric bromine chemistry and ozone budgets are studied. Destruction of the ozone layer chemicals responsible for this to be named but reactions not required. Since india already receives high doses of ultraviolet uvb radiation, and is at the threshold go to speak, effects of ozone layer depletion. Title vi for stratospheric ozone protection, signed into law. Chapter 2 notes chapter 2 is a discussion of the problem of stratospheric ozone and its depletion by photochemical reactions with chlorine containing molecules.

In this lesson, students will develop an explanation for the consequences of ozone depletion on earth by planning and carrying out an investigation. The most prominent reactions are the ho x, no x, and cl radical chain reactions these reactions are termed chain reactions because the ozonedestroying radical e. The chemistry of ozone depletion is driven by energy associated with sunlight. Ozone is bad in the troposphere because it is harmful to breathe and is the primary component of smog in summer. Ozone in the stratosphere is necessary to life as we know it because it absorbs energetic uv radiation. How severe is the depletion of the antarctic ozone layer. Students will use analysis and interpretation of data to develop a model to explain the cause and effect of ozone depletion on the planet earth. This extreme stability allows cfcs to slowly make their way into the stratosphere most molecules decompose before. Due to its environmental significance, the chemistry of atmospheric ozone and ozone depletion has been a subject of much research and discussion. In fact, the 1995 nobel prize in chemistry was awarded to three scientists who revealed the role of manmade chemicals, chlorofluorocarbons, or cfcs, in the ozone depletion process. Evs global warming, ozone depletion ppt ozone depletion.

Ozone depletion, gradual thinning of earths ozone layer in the upper atmosphere caused by the release of chemical compounds containing gaseous chlorine or bromine from industry and other human activities. Destruction of the upper atmospheric layer of ozone gas, caused by substances formed from breakdown of ozone depleting substances. Ozone in the troposphere is toxic due to its reactive oxidizing capabilities. Sherwood rowland, mario molina rowlands postdoc at the time, and paul crutzen and in 1995 they received the nobel prize for their work. Yet in a new study published in atmospheric chemistry and physics, scientists report that one crucial section of the ozone layer still seems to be declining steadily. Ozone in the stratospherea layer of the atmosphere between 15 and 50 kilometers 10 and 31 miles above usacts as a. This was also the start of intensive research into the chemistry of the atmosphere. Ozone is good in the stratosphere because it absorbs all of the most energetic ultraviolet radiation uvc, most of the uvb radiation and some of the least energetic uv radiation uva. Causes of ozone layer depletion and its effects on human. This timeline highlights the average area of the ozone hole between september 7th and october th as observed by nasa spacedbased instruments see colored bars and scale. These radiations can cause severe diseases in humans such as skin cancer, eye damage and genetic mutations etc 9. This note discusses the latest evidence on ozone depletion and uvr.

Ozone layer depletion the emission of ods account for roughly 90% of total depletion of ozone layer in stratosphere. Candidates will be asked to observe the effect of reagents andor of heat on substances supplied to them. Sulfuric acid h2so4 is the seed molecule for formation of stratospheric sulfate aerosol layer that assists ozone depletion by activation of halogen species. Ozone is formed throughout the atmosphere in multistep chemical processes. The ozone layer is a specific area in the stratosphere of maximum ozone concentration. Joe farman, brian gardiner, and jonathan shanklin british atlantic survey research station, holly bay, antarctic coast in 1985, using satellites, balloons,in 1985, using satellites, balloons, and surface stations, a team ofand surface stations, a team of researchers. It was only until recently, 1990s in fact, that the chemistry of ozone creation and destruction was developed by f. It is based on longer observational records, new chemistry. Copy the html code below to embed this book in your own blog, website, or application. Chemistry of ozone depletion cfc molecules are made up of chlorine, fluorine and carbon atoms and are extremely stable. Thousands of ozone molecules are being destroyed through this chain reaction.

Pdf ozone depletion is an emerging issue as it occurs with variation of. Ozone depletion consists of two related events observed since the late 1970s. Reactions 1 and 2 are elementary reactions, that is, they cannot be subdivided into two or more simpler reactions. Computer models of the atmo sphere employing this information. Besides carbon dioxide, other greenhouse gases are methane, water vapour, nitrous oxide, cfcs and ozone. Ozone in the stratosphere forms naturally and protects us from damage that can be caused by solar radiation such as skin cancer. Measurements from satellitebased instruments show that this area of very low ozone concentration has developed over antarctica every year since about 1975. The oxygen atom reacts quickly with water to form 2 molecules of hydroxyl in a bimolecular reaction reaction involving two reactants. In middle latitudes it is preferable to speak of ozone depletion rather than holes. Chapter 2 notes chapter 2 is a discussion of the problem. Thethe discoverydiscovery team who discovered the hole 1985. Thus, tropospheric chemistry has an impact on ozone in the stratosphere by controlling ho levels in the troposphere. These advances add to the scientific basis for decisions made by the parties to the montreal protocol.

The emission of ozone depleting substances has been damaging the ozone layer. Climate change is the greatest threat facing our planet today. Ozone depletion over india with so much worry about the rapid ozone depletion taking place in various parts of the earth, indian scientists are closely monitoring the ozone layer over india for possible depletion trends. Montreal protocol on substances that deplete the ozone layer. The tropospheric trace gases that contribute to in situ photochemical ozone production, or that influence tropospheric ho levels, include. Ozone depletion, gradual thinning of earth s ozone layer in the upper atmosphere caused by the release of chemical compounds containing gaseous chlorine or bromine from industry and other human activities. From an environmental standpoint, ozone is a confusing molecule. It has the ability to absorb the uv rays which occupy the ultraviolet region which ranges between. An uncorrected copy, or prepublication, is an uncorrected proof of the book. The halogenoalkanes or alkyl halides are a group of organic compounds derived from alkanes containing one or more halogens. Pdf causes of ozone layer depletion and its effects on. Ozone depletion describes two distinct but related phenomena observed since the late 1970s. We publish prepublications to facilitate timely access to the committees findings. Ozone depletion facts and information national geographic.

Although natural phenomenon can cause ozone depletion but human activities such as cfcs are now accepted as major cause of depletion 9. The latter phenomenon is referred to as the ozone hole. They have the general formula rx where r is an alkyl or substituted alkyl group and x is a halogen f, cl, br, i. The oxygen atom generated at the decomposition of clo combines with ozone to decompose it into oxygen molecule. These compounds are generally used as flame retardants, fire extinguishants, refrigerants, propellants. If the ozone layer is depleted by human action, the effects on the planet could be catastrophic. An oxygen molecules is photolyzed by solar radiation, creating two oxygen radicals. The first manmade threat to the ozone layer was noted by harold johnston 1971.

The thinning is most pronounced in the polar regions, especially over antarctica. Chlorofluorocarbons ozone depletion occurs when the natural balance between the production and destruction of stratospheric ozone is disturbed. Oxygen radicals then react with molecular oxygen to produce ozone. The chlorine atom is regenerated from clo and combines with another ozone molecule. Carbon dioxide is the major contributor to global warming. There are also springtime polar tropospheric ozone depletion. Environmental chemistry 401 carbon dioxide crosses the delicate proportion of 0. Industrial chemistry notes rohan barar 2016 1 industrial chemistry notes. It is important to note that scientific knowledge of the atmosphere and.

But in the stratosphere, the region of the atmosphere from 6 to 31 miles, ozone absorbs potentially. The ozone layer helps to protect life from harmful ultraviolet radiation. Even though longerlived ozone depleting substances provide the majority of the. The chemical reactions causing this ozone depletion are primarily based on atomic cl and clo, the product of its reaction with ozone. But through domestic and international action, the ozone layer is healing and should fully recover by about 2065. A twodimensional chemistrytransport model of the global troposphere is used to study the chemical response to i increased uv radiation from stratospheric ozone depletion and ii increased. The chemistry by which cfcs break down ozone is an extremely complicated process. Climate is the average weather at a given point and time of year, over a long period typically 30 years.

Tropospheric bromine chemistry and its impacts on ozone. The global exchange between ozone and oxygen is on the order of 300 million tons per day. The ozone layer protects the earth from the ultraviolet rays sent down by the sun. Twenty questions and answers about the ozone layer noaaesrl. Prezi s director of product marketing on working from home and finding balance.

Ozone in its pure state is blue in color which has a strong disturbing smell. Effects of ozone depletion ozone depletion is affecting the human health and environment negatively, as it allows the penetration of uv radiations to reach the earth. The ozone hole is an area where the amount of ozone in the upper atmosphere is much lower than normal. Find out what caused the ozone hole, and how the 1989 montreal protocol sought to put an end to ozone depletion.

Montreal protocol on substances that deplete the ozone layer 2012. See more ideas about ozone depletion, ozone layer and climate change. Note that emissions of the minor very shortlived bromocarbons ch2clbr, chcl2br. Yet new ozonedepleting compounds threaten this recovery, with implications for human health and marine ecosystems. This website addresses stratospheric ozone issues, including the science of ozone depletion, epas regulatory approach to protecting the ozone layer, epa.

This quick video discusses the role of the ozone layer and how cfcs can cause ozone depletion. The primary tools used in this assessment for prediction of ozone are chemistryclimate models ccms. In addition to uv absorption and oxygen radical reaction see chapman reactions, ozone can be destroyed by combination with other radical species. This ozone loss occurs in the temperate zone latitudes in all seasons, and especially drastically since the early 1980s in the south polar springtimethe antarctic ozone hole. This bad ozone forms when sunlight initiates chemical reactions in the. Ozone then reacts with an additional oxygen radical to form molecular oxygen.